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Consider a unit cell of 2 x 2 x 2 lattice constants; this contains 64 atoms. The (almost ridiculously small) simplest quantum dot that could be placed within this unit cell would be just one atom. Taking silicon as the host material and germanium as the dot, then this particular case is just the isoelectronic impurity dealt with earlier (see 11). However, in this case, the single Ge atom will be placed at the extreme corner of the unit cell (see Fig. 13.10), which will show the equivalence with the previous example, and will also be the approach used for subsequent calculations. This method of choosing the unit cell is somewhat easier than that used in the quantumwire calculations described earlier in this chapter. After choosing the unit cell, which in turn determines the reciprocal lattice vectors in the expansion set, then the empirical pseudopotential method can yield information such as the energy of the uppermost valence-band state or the lowest conduction-band state. These are illustrated for this simple example in Fig. 13.11. In addition, it is possible to plot the charge density for any state or number of states (see Fig. 13.12).

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Increment Menu Resource Index Whenever you change the CTC le, it is necessary to increment the second integer in this line in DslPackage\GeneratedCode\Packagett (You do not need to do this when you are changing the code in the handlers of a command you have already de ned)

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Figure 13.12 The difference in the total valence-band charge density between the 'tiny' quantum dots and bulk Si for different numbers of Ge atoms: (top left) 1; (top right) 4; (bottom left) 6; and (bottom right) 8

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Note that the plots are centred on the point occupied by the single Ge atom in Fig. 13.10 (left). 13.7 PYRAMIDAL QUANTUM DOTS As mentioned in 8, the deposition of a thin layer of one material on top of a substrate where there is a large difference in lattice constants, can lead to the formation of pyramidal-shaped quantum dots. These quantum dots can be quite large, perhaps a few hundred Angstroms across, and are totally beyond the range of direct diagonalisation of the empirical pseudpotential Hamiltonian matrix. However, solution has been achieved by using the folded-spectrum method [271].

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[VSShell::ProvideMenuResource(1000, /* Increment this: */ 5)]

The setting up of such a calculation requires a knowledge of the atomic positions, so with this aim, consider the schematic representation of a pyramidal dot shown in Fig. 13.13. Allowing the dot of base length B and height H to be encased within a cubic unit cell of side A + B + A, then the equations of the planes represented by the diagonally sloping sides in the right hand diagram of Fig. 13.13 are as follows:

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This causes the Visual Studio menu cache to be reset when the package builds or installs As we mentioned earlier, Provide attributes on the package are executed by regpkg during a build The ProvideMenuResource attribute runs the compiled version of the CTC le This places the commands into the Visual Studio command cache The cache persists between runs of VS; this is because some packages require their commands to be visible even before the package is loaded so that a command can load and start its package Because executing the cache update can be a lengthy operation, the ProvideMenuResource attribute doesn t bother unless it notices a change of version Running devenv/setup has the effect of rerunning all the command attributes for all the known packages

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